| ETTU Europe Trophy - Kobiety | 2022/06/19 09:30 | Aikaterini Toliou v Mitsuki Yoshida | W | 3-2 |
| ETTU Europe Trophy - Kobiety | 2022/06/18 11:05 | Aikaterini Toliou v Katarina Strazar | W | 3-0 |
| WTT Contender - Zagrzeb - Kobiety - walifikacje | 2022/06/13 13:30 | Swastika Ghosh v Aikaterini Toliou | L | 3-2 |
| WTT Singapore Smash - Kobiety | 2022/03/08 09:00 | Aikaterini Toliou v Sibel Altinkaya | L | 0-3 |
| WTT Feeder Dusseldorf - Kobiety | 2022/01/19 11:45 | Aikaterini Toliou v Christina Kallberg | L | 0-4 |
| WTT Feeder Dusseldorf - Kobiety | 2022/01/18 17:10 | Aikaterini Toliou v Gaia Monfardini | W | 3-2 |
| World Championship Women | 2021/11/23 19:00 | Adriana Diaz v Aikaterini Toliou | L | 4-0 |
| European Team Championships - Kobiety | 2021/09/29 10:40 | Polina Mikhaylova v Aikaterini Toliou | L | 3-1 |